1,105 research outputs found

    Towards Grower-friendly Apple Crop Thinning by Tree Shading

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    Light management with shading nets, which reduce sunlight by 74%, might be an alternative to chemicals commonly used for thinning on apple trees. To study the effect of shading on crop load and fruit quality, trials were conducted in field experiments with the cultivars Golden Delicious and Elstar in 2006. Trees were either covered 25 days after full bloom (DAFB) with a net during three days, or until the peak of fruit fall, observed after seven days shading. Ideal time length for optimal crop yield was seven days shading for Elstar and three days shading for Golden Delicious. Alternate bearing could be decreased as flower initiation counts the following year showed. In both experiments, inner quality of fruit such as sugar and firmness showed good values at optimal shading duration compared with chemical + hand thinning. In 2007, a second field trial was conducted with cultivars Golden Delicious and Topaz to study the time period for shading in further detail. Shading was done for three days at 19, 26 and 33 DAFB using two net types (three- and two-meter-net width, covering the trees entirely or only down to 50 cm above ground). For Golden Delicious, shading after 19 and 26 days reduced fruits per 100 flower cluster to the same extent as with chemical + hand thinning. There was no difference between the two net types. For Topaz, shading after 19 days showed the best results. Regarding inner quality of both cultivars, only sugar content for Golden Delicious could be significantly improved after 19 and 26 days shading. Further analyses are still under way (e.g. for acidity). This study is part of an effort for increasing European consumption with fruit from sustainable production systems, the ISAFRUIT-EU-project

    Relações de causa e efeito entre condições ambientais, urediniósporos e severidade de ferrugem-asiática da soja.

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    O objetivo deste trabalho foi estabelecer relações entre condições ambientais, o número de urediniósporos de Phakopsora pachyrhizi e a severidade da ferrugem-asiática-da-soja. Para quantificar urediniósporos de P. pachyrhizi, coletores foram instalados em campos de soja, em Itambé e Mandaguari, PR. Avaliações de severidade foram realizadas e dados climáticos foram coletados nos dois locais. As variáveis elaboradas foram: número de dias com umidade favorável (>60%), número de dias com temperatura favorável (18 a 32º C), preciptação acumulada e urediniósporos coletados. Uma variável baseada no controle químico também foi elaborada. Correlações entre as variáveis foram estimadas. A análise de trilha foi empregada para desdobrar as correlações. Cerca de 76% da variação das relações de causa e efeito entre as variáveis foi explicada pela análise de trilha. O número de dias para efetuar o controle químico teve efeito direto sob a severidade. O número de dias com temperatura favorável e as precipitações tiveram efeito indireto na severidade, atuando via manutenção de condições favoráveis de umidade

    Systematic motions in the Galactic plane found in the Hipparcos Catalogue using Herschel's Method

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    Two motions in the galactic plane have been detected and characterized, based on the determination of a common systematic component in Hipparcos catalogue proper motions. The procedure is based only on positions, proper motions and parallaxes, plus a special algorithm which is able to reveal systematic trends. Our results come from two stellar samples. Sample 1 has 4566 stars and defines a motion of apex (l,b)=(177.8,3.7)+/-(1.5,1.0) and space velocity V=27+/-1 km/s. Sample 2 has 4083 stars and defines a motion of apex (l,b)=(5.4,-0.6)+/-(1.9,1.1) and space velocity V=32+/-2 km/s. Both groups are distributed all over the sky and cover a large variety of spectral types, which means that they do not belong to a specific stellar population. Herschel's method is used to define the initial samples of stars and later to compute the common space velocity. The intermediate process is based on the use of a special algorithm to determine systematic components in the proper motions. As an important contribution, this paper sets out a new way to study the kinematics of the solar neighborhood, in the search for streams, associations, clusters and any other space motion shared by a large number of stars, without being restricted by the availability of radial velocities.Comment: 12 pages and 12 eps figures. LaTe

    Third-Generation W(CNAr)₆ Photoreductants (CNAr = Fused-Ring and Alkynyl-Bridged Arylisocyanides)

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    Homoleptic tungsten(0) arylisocyanides possess photophysical and photochemical properties that rival those of archetypal ruthenium(II) and iridium(III) polypyridine complexes. Previous studies established that extending the π-system of 2,6-diisopropylphenylisocyanide (CNDipp) by coupling aryl substituents para to the isocyanide functionality results in W(CNDippAr)₆ oligoarylisocyanide complexes with greatly enhanced metal-to-ligand charge transfer (MLCT) excited-state properties relative to those of W(CNDipp)₆. Extending electronic modifications to delineate additional design principles for this class of photosensitizers, herein we report a series of W(CNAr)₆ compounds with naphthalene-based fused-ring (CN-1-(2-ⁱPr)-Naph) and CNDipp-based alkynyl-bridged (CNDipp^(CC)Ar) arylisocyanide ligands. Systematic variation of the secondary aromatic system in the CNDippCCAr platform provides a straightforward method to modulate the photophysical properties of W(CNDipp^(CC)Ar)₆ complexes, allowing access to an extended range of absorption/luminescence profiles and highly reducing excited states, while maintaining the high molar absorptivity MLCT absorption bands, high photoluminescence quantum yields, and long excited-state lifetimes of previous W(CNAr)₆ complexes. Notably, W(CN-1-(2-iPr)-Naph)₆ exhibits the longest excited-state lifetime of all W(CNAr)₆ complexes explored thus far, highlighting the potential benefits of utilizing fused-ring arylisocyanide ligands in the construction of tungsten(0) photoreductants

    Third-Generation W(CNAr)₆ Photoreductants (CNAr = Fused-Ring and Alkynyl-Bridged Arylisocyanides)

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    Homoleptic tungsten(0) arylisocyanides possess photophysical and photochemical properties that rival those of archetypal ruthenium(II) and iridium(III) polypyridine complexes. Previous studies established that extending the π-system of 2,6-diisopropylphenylisocyanide (CNDipp) by coupling aryl substituents para to the isocyanide functionality results in W(CNDippAr)₆ oligoarylisocyanide complexes with greatly enhanced metal-to-ligand charge transfer (MLCT) excited-state properties relative to those of W(CNDipp)₆. Extending electronic modifications to delineate additional design principles for this class of photosensitizers, herein we report a series of W(CNAr)₆ compounds with naphthalene-based fused-ring (CN-1-(2-ⁱPr)-Naph) and CNDipp-based alkynyl-bridged (CNDipp^(CC)Ar) arylisocyanide ligands. Systematic variation of the secondary aromatic system in the CNDippCCAr platform provides a straightforward method to modulate the photophysical properties of W(CNDipp^(CC)Ar)₆ complexes, allowing access to an extended range of absorption/luminescence profiles and highly reducing excited states, while maintaining the high molar absorptivity MLCT absorption bands, high photoluminescence quantum yields, and long excited-state lifetimes of previous W(CNAr)₆ complexes. Notably, W(CN-1-(2-iPr)-Naph)₆ exhibits the longest excited-state lifetime of all W(CNAr)₆ complexes explored thus far, highlighting the potential benefits of utilizing fused-ring arylisocyanide ligands in the construction of tungsten(0) photoreductants

    Brown dwarfs in the Hyades and beyond?

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    We have used both the Low-Resolution Imaging Spectrograph and the HIRES echelle spectrograph on the Keck telescopes to obtain spectra of twelve candidate members of the Hyades cluster identified by Leggett and Hawkins (1988, 1989). All of the objects are chromospherically-active, late-type M-dwarfs, with Hα\alpha equivalent widths varying from 1 to 30\AA. Based on our measured radial velocities, the level of stellar activity and other spectroscopic features, only one of the twelve stars has properties consistent with cluster membership. We consider how this result affects estimates of the luminosity and mass function of the Hyades cluster. Five of the eleven field stars have weak K I 7665/7699\AA and CaH absorption as compared with M-dwarf standards of the same spectral type, suggesting a lower surface gravity. Two of these sources, LH0416+14 and LH0419+15, exhibit significant lithium 6708 \AA absorption. Based partly on parallax measurements by the US Naval Observatory (Harris et al, 1998), we identify all five as likely to be young, pre-main sequence objects in or near the Taurus-Auriga association at distances of between 150 and 250 parsecs. A comparison with theoretical models of pre-main sequence stars indicates masses of less than 0.05 M_\odot.Comment: to appear in AJ, January 1999; 34 pages, (Latex format), including 10 embedded postscript figures and two table

    The prolate-to-oblate shape transition of phospholipid vesicles in response to frequency variation of an AC electric field can be explained by the dielectric anisotropy of a phospholipid bilayer

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    The external electric field deforms flaccid phospholipid vesicles into spheroidal bodies, with the rotational axis aligned with its direction. Deformation is frequency dependent: in the low frequency range (~ 1 kHz), the deformation is typically prolate, while increasing the frequency to the 10 kHz range changes the deformation to oblate. We attempt to explain this behaviour with a theoretical model, based on the minimization of the total free energy of the vesicle. The energy terms taken into account include the membrane bending energy and the energy of the electric field. The latter is calculated from the electric field via the Maxwell stress tensor, where the membrane is modelled as anisotropic lossy dielectric. Vesicle deformation in response to varying frequency is calculated numerically. Using a series expansion, we also derive a simplified expression for the deformation, which retains the frequency dependence of the exact expression and may provide a better substitute for the series expansion used by Winterhalter and Helfrich, which was found to be valid only in the limit of low frequencies. The model with the anisotropic membrane permittivity imposes two constraints on the values of material constants: tangential component of dielectric permittivity tensor of the phospholipid membrane must exceed its radial component by approximately a factor of 3; and the membrane conductivity has to be relatively high, approximately one tenth of the conductivity of the external aqueous medium.Comment: 17 pages, 6 figures; accepted for publication in J. Phys.: Condens. Matte

    Exploiting variability for energy optimization of parallel programs

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    In this paper we present optimizations that use DVFS mechanisms to reduce the total energy usage in scientific applications. Our main insight is that noise is intrinsic to large scale parallel executions and it appears whenever shared resources are contended. The presence of noise allows us to identify and manipulate any program regions amenable to DVFS. When compared to previous energy optimizations that make per core decisions using predictions of the running time, our scheme uses a qualitative approach to recognize the signature of executions amenable to DVFS. By recognizing the "shape of variability" we can optimize codes with highly dynamic behavior, which pose challenges to all existing DVFS techniques. We validate our approach using offline and online analyses for one-sided and two-sided communication paradigms. We have applied our methods to NWChem, and we show best case improvements in energy use of 12% at no loss in performance when using online optimizations running on 720 Haswell cores with one-sided communication. With NWChem on MPI two-sided and offline analysis, capturing the initialization, we find energy savings of up to 20%, with less than 1% performance cost
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